Optical emission spectroscopic study of plasma plumes generated by IR CO2 pulsed laser on carbon targets

نویسندگان

  • J J Camacho
  • M L Poyato
چکیده

Optical emission spectroscopy studies, in the spectral range ultraviolet–visible–near infrared (UV–Vis–NIR), were performed to investigate thermal and dynamical properties of a plume produced by laser ablation of a graphite target. Ablation is carried out using a high-power IR CO2 pulsed laser at λ = 9.621μm, power density ranging from 0.22 to 5.36 GW cm−2 and air pressures around 4 Pa. The strong emission observed in the plasma region is mainly due to electronic relaxation of excited C, ionic fragments C+, C2+ and C3+ and molecular features of C2(d 3 g–a 3 u; Swan band system). The medium-weak emission is mainly due to excited atomic N, H, O, ionic fragment C4+ and molecular features of C2(E 1 + g –A 1 u; Freymark system), C2(D 1 + u –X 1 + g ; Mulliken system), CN(D 2 –A 2 ), C2(e 3 g–a 3 u; Fox–Herzberg system), C2(C 1 g–A 1 u; Deslandres–d’Azambuja system), OH(A 2 +–X 2 ), CH(C 2 +–X 2 ), NH(A 3 –X 3 −), CN(B 2 +–X 2 +; violet system), CH(B 2 +–X 2 ), CH(A 2 –X 2 ), C2(A 1 u–X 1 + g ; Phillips system) and CN(A 2 –X 2 +; red system). An excitation temperature Texc = 23 000 ± 1900 K and electron densities in the range (0.6–5.6)× 1016 cm−3 were estimated by means of C+ ionic lines. The characteristics of the spectral emission intensities from different species have been investigated as functions of the ambient pressure and laser irradiance. Estimates of vibrational temperatures of C2 and CN electronically excited species under various laser irradiance conditions are made. (Some figures in this article are in colour only in the electronic version)

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Temporal evolution of the laser-induced plasma generated by IR CO2 pulsed laser on carbon targets

Related Articles Characteristics of a cylindrical collector mirror for laser-produced xenon plasma soft X-rays and improvement of mirror lifetime by buffer gas Rev. Sci. Instrum. 83, 123110 (2012) Coherent microwave radiation from a laser induced plasma Appl. Phys. Lett. 101, 264105 (2012) Evidence for ultra-fast heating in intense-laser irradiated reduced-mass targets Phys. Plasmas 19, 122708 ...

متن کامل

Optical emission spectroscopy of oxygen plasma induced by IR CO2 pulsed laser

Laser-induced breakdown (LIB) spectroscopy in oxygen at room temperature and pressures ranging from 4.6 to 75 kPa was studied using a high-power transverse excitation atmospheric CO2 laser (λ = 9.621 and 10.591μm; τFWHM = 64 ns; power densities ranging from 0.87 to 6.31 GW cm−2). The spectrum of the generated plasma is dominated by emission of strong O, O+ and weak O2+ atomic lines. Excitation ...

متن کامل

Study on the correlation between plasma electron temperature and penetration depth in laser welding processes

The plasma electron temperature has been estimated starting from the spectroscopic analysis of the optical emission of the lasergenerated plasma plume during quite diverse stainless steel welding procedures (c.w. CO2 and pulsed Nd:YAG). Although the optical emissions present different spectral features, a discrete contribution of several iron lines can be highlighted in both types of welding. W...

متن کامل

Angular distribution of debris from CO2 and YAG laser- produced tin plasmas

We investigated the angular dependence of atomic and ionic debris from CO2 and YAG laser-produced tin plasmas. Several diagnostic techniques were employed for this study including a Faraday cup, witness plates and subsequent x-ray photoelectron spectroscopic analysis, optical emission spectroscopy etc. It was found that the debris emission from the Nd:YAG laser-produced plasmas fell sharply fro...

متن کامل

Plasma Characterization of Pulsed-Laser Ablation Process Used for Fullerene-like CNx Thin Film Deposition

An in situ Optical Emission Spectroscopy (OES) characterization was performed on Pulsed-Laser Ablation (PLA) process used for fullerene-like CNx thin film deposition at nitrogen pressures within the 5 – 100 mTorr range. Plumes were generated by ablation of pyrolytic graphite (99.99%) target using a (500 mJ, 7 ns, 1064 nm) Nd: YAG-pulsed laser. The spectra from the plume show, essentially, the p...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2008